Sodium Lauryl Sulphate
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Sodium Lauryl Sulfate (SLS) is a common synthetic detergent and surfactant. It's a white or cream-coloured powder that is used in a variety of personal care and cleaning products due to its ability to create foam and remove dirt and oils from surfaces. SLS is an anionic surfactant, which means it has a hydrophilic (water-attracting) head and a lipophilic (oil-attracting) tail. This structure allows it to break down oil and grease, making it effective in cleansing products.
While SLS is effective at cleaning, it can be harsh on some people's skin and hair, potentially causing dryness or irritation. As a result, some individuals with sensitive skin or certain hair types may prefer products that use milder surfactants or are SLS-free.
There has been some debate and concern about the safety of SLS, especially in high concentrations, but it is generally regarded as safe for use in cosmetics and personal care products when used as directed.
Surfactant: SLS is a powerful surfactant, meaning it lowers the surface tension of water, helping to mix water with oils and dirt. This property makes it effective in cleaning products like shampoos, body washes, and facial cleansers.
Foaming Agent: SLS is well-known for its ability to create a rich lather, which enhances the sensory experience of products like shampoos, toothpastes, and bubble baths. Consumers often associate foam with effective cleaning.
Emulsifier: In formulations containing both oil and water, SLS can act as an emulsifier, helping to stabilize and maintain the mixture, preventing separation over time.Wetting Agent: SLS improves the wetting properties of liquids, allowing them to spread more easily over surfaces. This is useful in products like mouthwashes and skin cleansers to ensure even application.
Dispersing Agent: It helps to disperse particles evenly in a formulation, which is beneficial in products like scrubs or exfoliants to ensure uniform distribution of abrasive materials.
Detergent: Due to its strong cleaning power, SLS is often used in formulations where effective removal of dirt, oils, and other impurities is required, such as in facial cleansers and household cleaning products.
Thickening Agent: SLS can contribute to the viscosity of a product, giving it a thicker consistency. This is particularly useful in shampoos and body washes, where a gel-like texture is desirable.
Use at Appropriate Concentrations: SLS is a strong surfactant and can be irritating at high concentrations. For leave-on products, use very low concentrations or consider alternative, milder surfactants. In rinse-off products, concentrations typically range from 0.5% to 10%, depending on the formulation and desired foaming ability.
Combine with Milder Surfactants: To reduce potential skin irritation, consider blending SLS with milder surfactants like Cocamidopropyl Betaine. This combination can soften the harshness of SLS while maintaining good foaming and cleansing properties.
pH Consideration: SLS is stable and effective in a wide pH range, but it's best to formulate products within a pH range of 5-7 to be gentle on the skin. Check the final pH of your product and adjust if necessary to avoid irritation.
Pre-dissolve SLS in Water: SLS is typically available in powder or granular form and should be fully dissolved in water before adding other ingredients. This helps ensure uniform distribution and reduces the risk of clumping.
Avoid Overheating: When heating your formulation, be cautious not to overheat SLS, as excessive heat can cause degradation and reduce its effectiveness. Add SLS to the aqueous phase at a controlled temperature, ideally below 50°C (122°F).
Consider Skin Sensitivity: If your target audience includes individuals with sensitive skin, use SLS cautiously or explore alternatives. SLS can cause dryness or irritation, especially in products intended for frequent use or for sensitive areas like the face.
Test for Compatibility: Ensure that SLS is compatible with other ingredients in your formulation, particularly in complex systems with active ingredients or oils. Conduct stability testing to ensure the final product remains stable over time.Formulation Transparency: If formulating clear or transparent products, be aware that SLS can sometimes cause cloudiness or affect the clarity of the final product. Adjust the concentration or consider adding clarifying agents if transparency is important.
Reduce Irritation Potential: Incorporate soothing agents or moisturizers, such as aloe vera, glycerin, or panthenol, in your formulation to counterbalance the potential drying effects of SLS.
Rinse-Off Formulations: SLS is most effective and less likely to cause irritation when used in rinse-off products like shampoos, body washes, and facial cleansers. For leave-on products, consider using gentler surfactants.
Chemical Name: Sodium Lauryl Sulphate
CAS Number: 151-21-3
Molecular Formula: C₁₂H₂₅NaO₄S
Molecular Weight: 288.38 g/mol
Synonyms: Sodium dodecyl sulfate, Sodium dodecyl sulphate, SDS (when in powder form)
Appearance: White to off-white powder or needles, sometimes available as a viscous liquid.
Odour: Slight characteristic odour
Solubility: Highly soluble in water; slightly soluble in ethanol
Melting Point: 204°C (399°F) (for anhydrous form)
pH (1% Solution): 7-9 (neutral to slightly alkaline)
Critical Micelle Concentration (CMC): Approximately 0.0082 M in water
Density: 0.3 – 0.5 g/cm³ (for powder form)
Foaming Ability: High; generates abundant foam in aqueous solutions
Surface Tension: 33-43 mN/m at CMC (varies with concentration and temperature)
Hydrophilic-Lipophilic Balance (HLB): 40 (highly hydrophilic)
Decomposition: Decomposes upon heating, releasing sulfur oxides
Stability: Stable under normal conditions; hydrolyzes slowly in strong acids and bases
Toxicity: Low to moderate toxicity; may cause skin and eye irritation upon direct contact
Irritancy: Known to be a skin and eye irritant, especially in high concentrations
Ecotoxicity: Harmful to aquatic life with long-lasting effects; not readily biodegradable
Handling Precautions: Avoid inhalation of dust; use protective gloves and eye protection when handling the raw material
Primary Use: Surfactant in detergents, shampoos, toothpastes, and other personal care products
Packaging: Available in bulk as powder, granules, or as a liquid concentrate
Storage: Store in a cool, dry place, away from moisture and strong oxidizing agents; keep container tightly closed to prevent contamination